パワーポイントスライドショー

Report
Low-vol.サンプリング
流量3~4L/min,24時間
約5m3 採取
Ps-Air1段目に、サロゲート
物質16ng(HCBはその2分の
1)を添加
Ps-Air
Hi-vol.サンプリング
流量700L/min,24時間
約1000m3 採取
ポリウレタンフォーム1段
目に、サロゲート物質を
16ng(HCBはその2分の
1)を添加
m
H
HC
a-
CB
-H
溶出試験(Hi-vol.)
13
C
aHC
13
H
Cbe
ta
-H
13
CH
Cr
in
g4,4
DD
8D
E
rin
g4,4
DD
13
D
C13
He
Cpt
he
ac
pt
hl
or
ac
hl
or
13
_e
po
Cxid
tra
e
ns
-c
13
hl
or
Cda
tra
ne
ns
-n
on
13
ac
hr
Col
ci
sno
na
ch
lo
r
ga
m
C-
13
lph
-a
13
C
比率(%)
Lc-Siカラムでのヘキサン溶出試験(Hi-vol.法)
hexan 20mlfr
hexan 10mlfr
100%
90%
80%
70%
60%
50%
40%
30%
20%
10%
0%
B
CHC
r
20%
13
40%
hl
o
no
na
c
ro
l
no
na
ch
ci
s-
13
C-
da
ne
or
po
xid
e
r_e
ch
l
ns
-
ns
-
tra
13
C-
tra
13
C-
lo
r
DD
,4D
DE
,4D
ta
ch
-H
ep
ch
lo
pt
a
-h
e
13
C
13
C
g4
rin
8D
H
-H
C
ta
CH
HC
H
aH
g4
rin
13
C
-b
e
13
C
m
m
-g
a
13
C
-a
lph
a-
13
C
比率(%)
Ps-Airでのジクロロメタン溶出試験(Low-vol.法)
溶出試験(Ps-Air)
100%
80%
60%
Dichlor
Dichlor
Dichlor
Dichlor
Dichlor
10mlfr
8mlfr
6mlfr
4mlfr
2mlfr
0%
<大気試料の分析例(Hi-Vol.)>
DQ Main View
Page 1
DqData : f:\0222-POPs-LOW-sample002.mfl\POPs LOW sample2\POPs LOW sample2
Injection : 2/18-19 HV pre hexan 10mlfr to 1ml
HCH
αーHCH
600000
Intensity
400000
γーHCH
200000
βーHCH
0
10.0
10.5
11.0
11.5
12.0
12.5
13.0
13.5
Retention Time (min)
14.0
14.5
15.0
15.5
16.0
13C-HCH
αー13C6-HCH
Intensity
400000
delta-HCH
beta-HCH
alpha-HCH
gamma-HCH
Calculated Retention Time
γー13C6-HCH
βー13C6-HCH
200000
0
10.0
10.5
11.0
11.5
12.0
12.5
13.0
13.5
Retention Time (min)
14.0
14.5
15.0
15.5
DQ Main View
16.0
Page 1
DqData : f:\0222-POPs-LOW-sample002.mfl\POPs LOW sample2\POPs LOW sample2
Injection : 2/18-19 HV pre hexan 10mlfr to 1ml
DDD
120000
o,p’-DDD
Intensity
80000
p,p’-DDD
40000
0
24.0
24.4
24.8
25.2
25.6
26.0
26.4
26.8
Retention Time (min)
27.2
27.6
28.0
28.4
28.8
4,4'-DDD
1,4'-DDD
Calculated Retention Time
Ring-13C12-p,p’-DDD
8Dring-4,4DDD
Intensity
800000
400000
0
24.0
24.4
24.8
25.2
25.6
26.0
26.4
26.8
Retention Time (min)
27.2
27.6
28.0
28.4
28.8
DQ
Main
View
Page
DqData : f:\0222-POPs-LOW-sample002.mfl\POPs
Injection : 2/18-19 HV pre hexan 10mlfr to 1ml
LOW
sample2\POPs
Heptachlor
30000
LOW
1
sample2
heptachlor
25000
Intensity
20000
15000
10000
5000
0
13.6
Retention
13.8
14.0
14.2
14.4
14.6
Retention
14.8
Time
13C-Heptachlor
15.2
15.4
15.6
15.8
16.0
15.4
15.6
15.8
16.0
13C 10
heptachlor
120000
Intensity
15.0
(min)
Time
Heptachlor
Calculated
80000
40000
0
13.6
DQ
Main
13.8
14.0
14.2
14.4
14.6
Retention
14.8
Time
15.0
(min)
15.2
View
Page
DqData : f:\0222-POPs-Hi-sample002.mfl\POPs
Injection : 2/18-19 HV hexan10mlfr to 1ml
Hi
sample2\POPs
heptachlor-epoxide
Hi
sample2
Heptachlor epoxide
16000
Intensity
12000
8000
4000
18.0
Retention
18.4
18.8
19.2
19.6
20.0
20.4
Retention Time (min)
20.8
21.2
21.6
22.0
Time
heptachlor_epoxide
Calculated
13C-heptachlor-epoxide
13C -heptachlor-epoxide
10
Intensity
400000
200000
0
18.0
18.4
18.8
19.2
19.6
20.0
20.4
Retention Time (min)
20.8
21.2
21.6
22.0
1
DQ
Main
View
Page
DqData : f:\0222-POPs-Hi-sample002.mfl\POPs
Injection : 2/18-19 HV hexan10mlfr to 1ml
Hi
sample2\POPs
Hi
sample2
chlordane
400000
Intensity
compound5
t-chlordane
300000
c- chlordane
200000
100000
0
20.0
20.4
20.8
21.2
21.6
22.0
22.4
Retention Time (min)
22.8
23.2
23.6
24.0
24.4
22.8
23.2
23.6
24.0
24.4
13C -t10
13C-chlordane
40000
chlordane
cis-chlordane
Time
compound-5
Retention
trans-chlordane
Calculated
Intensity
30000
20000
10000
0
20.0
20.4
20.8
21.2
21.6
22.0
22.4
Retention Time (min)
DQ Main View
Page 1
DqData : f:\0222-POPs-Hi-sample002.mfl\POPs Hi sample2\POPs Hi sample2
Injection : 2/18-19 HV hexan10mlfr to 1ml
nonachlor
t-nonachlor
160000
compound6
Intensity
120000
c-nonachlor
80000
40000
0
20
21
22
23
24
25
Retention Time (min)
26
27
23
24
25
Retention Time (min)
26
27
28
cis-nonachlor
trans-nonachlor
Calculated Retention Time
13C-nonachlor
Intensity
300000
200000
100000
0
20
21
22
28
1
DQ Main View
Page 1
DqData : f:\0222-POPs-Hi-sample002.mfl\POPs Hi sample2\POPs Hi sample2
Injection : 2/18-19 HV hexan10mlfr to 1ml
HCB
HCB
Intensity
3000000
2000000
1000000
0
9.6
10.0
10.4
10.8
Retention Time (min)
11.2
11.6
12.0
11.2
11.6
12.0
HCB
Calculated Retention Time
13C
13C-HCB
Intensity
80000
6-
HCB
40000
0
9.6
10.0
10.4
10.8
Retention Time (min)
【大気中濃度測定例】
他の測定例
本検討での測定例
Ps-Air
alpha-HCH
gamma-HCH
beta-HCH
delta-HCH
aldrin
dieldrin
endrin
o,p'-DDE
p,p'-DDE
o,p'-DDD
p,p'-DDD
o,p'-DDT
p,p'-DDT
Heptachlor
heptachlor_epoxide
trans-chlordane
cis-chlordane
trans-nonachlor
cis-nonachlor
HCB
N.D.
N.D.
N.D.
N.D.
N.D.
N.D.
N.D.
N.D.
N.D.
N.D.
N.D.
N.D.
N.D.
0.17
N.D.
0.025
0.012
N.D.
N.D.
0.097
Hi-vol.
(石英繊維ろ
紙使用)
0.019
0.0051
0.0025
N.D.
N.D.
N.D.
N.D.
N.D.
0.0033
0.00074
0.0012
0.0047
0.0090
0.0057
0.0006
0.018
0.015
0.016
0.0020
0.034
Hi-vol.
(活性炭繊維ろ
紙使用)
0.041
0.013
0.0071
N.D.
N.D.
N.D.
N.D.
N.D.
0.0028
N.D.
N.D.
0.010
0.0093
0.091
N.D.
0.12
0.10
0.17
0.011
0.10
新潟
(2000.7~
神戸
2001.7平均) (1995.2)
N=49
USA
Antarctica
galveston
(1994)
(1995) N=25 N=52?
0.092
0.023
0.032
0.003
0.13
0.043
0.0039
<0.5
0.079
0.14
0.004
0.047
0.061
0.012
0.0004
0.0049
0.0093
0.053
0.011
0.00052
<0.002
0.002
0.006
0.091
0.088
0.0076
0.00017
0.078
0.064
0.12
0.12
0.066
0.03
0.038
0.006
0.0013
0.16
0.17
0.087
0.056

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